Help, please: Dark spots

garcia

New Member
Joined
Feb 5, 2008
Messages
2
Dark spots appear on the backside of my sterling silver buckles after they age a bit. Noticeable because there is no engraving there. I pickle with diluted sulphuric acid (battery acid). Any suggestions would help. Thanks.
 

Daniel Houwer

Elite Cafe Member
Joined
Mar 21, 2007
Messages
239
Location
Holland
Hi Garcia,
That is sterling for you I think. The copper in the alloy tarnishes with a little moisture.
Sometimes it helps to pickle the buckle when hot and then burnish it but that is too much work.
The hot pickling creates a very thin fine silver surface and the burnishing wil close the pores.
Normaly the black spots will be easy to remove with a silvercloth with some polishing fluid.

If you have nasty deep black spots they will be firescale stains produced whenn soldering. If you use a good surface covering boraxlayer whenn soldering the stains will be a lot less deep or not there at all.

Daniel
 

monk

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Staff member
::::Pledge Member::::
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Feb 11, 2007
Messages
10,870
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washington, pa
battery acid i'm sure is not too pricey, but what kind of junk does it bring with it ? maybe that could be part of the problem.
 

Powderhorn

Elite Cafe Member
Joined
May 24, 2007
Messages
274
Location
Henderson, NV
garcia;
First thing is to get rid of the Sulfuric Acid, use Spyrex, it's a lot safer, and does not tend to eat holes in clothes.
As for the oxidation, a quick, simple trick is, after polishing, is to use something like Pledge or equivalent furniture polish on it. It will stop the oxidation of the silver. The other alternative is to use something like Rio Grande, Midas Tarnish Shield.
 

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